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Frequency offset effects and their elimination in NMR rotating-frame cross-relaxation spectroscopy

โœ Scribed by C Griesinger; R.R Ernst


Publisher
Elsevier Science
Year
1987
Weight
689 KB
Volume
75
Category
Article
ISSN
0022-2364

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The effect of an offset term in the cross-polarization (CP) Hamiltonian of a heteronuclear spin-12 pair due to off-resonant radio frequency (rf) irradiation and/or chemical shift anisotropy on one of the rf channels is investigated. Analytical solutions, simulations, and experimental results are pre