✦ LIBER ✦

Frequency dependence of intermolecular proton spin-lattice relaxation rate and pair-diffusion constant in neat acetonitrile -d2

✍ Scribed by Tadashi Tokuhiro; Juanita Freer; K.W. Woo

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 339 KB
Volume: 65
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)80303-6

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✦ Synopsis

Frcquenw dependence of intermolecular proton spin--lattice relaxation r&e [(IiT,) intq,)j in ntit axxonitrilcil:: \a studied. From (1/2-tfifi'Cr(w) pair-diffusion constants wxe determined to be 0 281 X 10v5 and 0 237 X 10e5 cm2 s-l at 22 and -32.6QC, respectikely. These valurs differ greatly from the scffkiiffusion constants. When Harmon and bf ulIer (HM) [ I] extended Torrey's theory 121 for nucIear spin-Iattice relaxation

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