The electron paramagnetic resonance pulsed free induction decay (FID) of a degassed solution of a triaryl methyl radical, methyl tris(8-carboxy-2,2,6,6-tetramethyl(-d3)-benzo[1,2-d:4,5-d']bis(1,3)dithiol-4-yl) tripotassium salt, 0.2 mM in H2O, was measured at VHF (247.5 MHz) and L-band (1.40 GHz). T
Frequency Dependence of EPR Signal-to-Noise
โ Scribed by George A. Rinard; Richard W. Quine; James R. Harbridge; Ruitian Song; Gareth R. Eaton; Sandra S. Eaton
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 108 KB
- Volume
- 140
- Category
- Article
- ISSN
- 1090-7807
No coin nor oath required. For personal study only.
โฆ Synopsis
Direct measurements of electron spin-echo signal and noise in well-characterized X-band and S-band spectrometers agree with predictions of frequency dependence based on first principles. For the particular spectrometers compared, the echo at 9.52 GHz was 9.5 times larger than the echo at 2.68 GHz, after scaling for differences in spectrometer gain. The calculated ratio was 7.6. This result contrasts with prior predictions that the frequency dependence would be much greater.
๐ SIMILAR VOLUMES
Experimental EPR signal intensities at 250 MHz, 1.5 GHz, and 9.1 GHz agree within experimental error with predictions from first principles. When both the resonator size and the sample size are scaled with the inverse of RF/microwave frequency, ฯ, the EPR signal at constant B 1 scales as ฯ -1/4 . Co