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Fremy's salt oxidation of benzylamines. An oxidative deamination reaction

✍ Scribed by Luis Castedo; Ricardo Riguera; M.Jesús Rodriguez


Book ID
103399007
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
191 KB
Volume
38
Category
Article
ISSN
0040-4020

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Oxidation of indolines with Fremy's salt
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Oxidation of an indoline with Fremy's salt (potassium nitrosodisulfonate) led to the formation of an unstable intermediate which isomerized to the desired 5-hydroxyindole upon standing. This intermediate has been isolated and characterized as an iminoquinone derivative. Identification of this interm