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Free-Volume Theory Applied to Diffusion in Liquids: A Critical Analysis

โœ Scribed by Mauviel, Guillain; Favre, Eric


Book ID
126427508
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
126 KB
Volume
43
Category
Article
ISSN
0888-5885

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Several versions of free-volume theory have been proposed to correlate or predict the solvent diffusion coefficient of a polymer/solvent system. The quantity of free volume is usually determined by the Williams-Landel-Ferry (WLF) equation from viscosity data of the pure component in these theories.