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Free radicals in the reduction of gem-dialkylcyclohexadienones in acid media

✍ Scribed by A. I. Prokof'ev; N. N. Bubnov; S. P. Solodovnikov; T. I. Prokof'eva; A. A. Volod'kin; V. V. Ershov

Book ID
112440324
Publisher
Springer
Year
1975
Tongue
English
Weight
172 KB
Volume
24
Category
Article
ISSN
1573-9171

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Selective free-radical phenylations: nit
Selective free-radical phenylations: nitrogen-heteroaromatic compounds in acidic media
✍ Henri J.M. Dou; Brian M. Lynch πŸ“‚ Article πŸ“… 1965 πŸ› Elsevier Science 🌐 French βš– 192 KB

R. D. Brown (1) has shown that molecular-orbital calculations of localleatlon energies satlsfaotorlly reproduoe the observed partial rate factors for substitution of pyrldlne by phenyl radicals. Similar calculations for the pyrldlnlum Ion (2) suggest greatly enhanced reactivity at the P-position