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Free radicals in the reactions of orthoquinones with certain transition-metal acetylacetonates

✍ Scribed by S. G. Kukes; A. I. Prokof'ev; A. S. Masalimov; N. N. Bubnov; S. P. Solodovnikov; M. I. Kabachnik


Book ID
112442027
Publisher
Springer
Year
1978
Tongue
English
Weight
445 KB
Volume
27
Category
Article
ISSN
1573-9171

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✍ A. StaΕ‘ko; A. TkÑč; V. Laurinc; L. MalΓ­k πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 248 KB

## Abstract The anion radical of acetylacetonate is formed by the reaction of nickel (II) acetylacetonate with Grignard reagents. From the two coupling constants found in the e.s.r. spectrum, the one of 2Β·6 G was assigned to the methine proton and the one of 12Β·5 G to the six equivalent methyl prot