Free radicals in coals and coal conversion. 2. Effect of liquefaction processing conditions on the formation and quenching of coal free radicals
โ Scribed by Leon Petrakis; David W. Grandy
- Book ID
- 107755595
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 660 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0016-2361
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The nature and concentration of free radicals in natural and pyrolysed samples of several high-purity resinites, vitrinites and fusinites have been determined by electron spin resonance (e.s.r.) spectrometry. Careful measurements of theg-values, linewidths and integrated intensities have been made.
The results of conversion determinations on the products from Powhatan No.5 coal liquefied in an autoclave and in a high-pressure, high-temperature e.s.r. cavity are reported. Oil, asphaltene and preasphaltene yields, and overall conversion have been determined for Powhatan No.5 coal samples liquefi
The effects of pyrite (FeS,) and pyrrhotite (Fe+,) on free radical formation in a coal sample (81% carbon content) have been investigated by electron spin resonance (e.s.r.) spectroscopy. Changes in the e.s.r. parameters (spin concentration g-', n, linewidth M and g-value) were monitored in samples
In a continuing series of publications, a systematic investigation of the free radicals during coal depolymerization under SRC-II preheater/reactor conditions has been made. A uniquely designed electron spin resonance (e.s.r.) cavity allows the monitoring of free radicals and how they are affected b