Free-radical propagation rate coefficients for hydroxyalkyl methacrylates and cyclohexyl methacrylate
β Scribed by Hou-Hsein Chu; Juan-Dan Wu
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 172 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1022-9760
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π SIMILAR VOLUMES
Propagation rate coefficients (kp) for the homopolymerizations of butyl methacrylate (BMA) and dodecyl methacrylate (DMA) were determined by the pulsed laser polymerization (PLP)/size-exclusion chromatography (SEC) technique. At ambient pressure, the polymerizations of BMA and DMA were studied betwe
## Abstract Pulsedβlaser polymerization (PLP) in conjunction with molar mass distribution (MMD) measurement is the method of choice for determining the propagation rate coefficient __k__~p~ in freeβradical polymerizations. The authors, members of the IUPAC Working Party on __Modeling of kinetics an
The propagation rate coefficient in free-radical bulk polymerization of butyl methacrylate has been studied at temperatures between -10Β°C and 60 "C up to a maximum pressure of 2000 bar. The data were obtained by means of the PLP-GPC technique which combines pulsed-laser polymerization with product a