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Free-radical products of the interaction of peroxide radicals with amines

✍ Scribed by E. G. Furman; T. M. Abramova; I. A. Spirina; A. S. Fomenko


Book ID
112362752
Publisher
Springer
Year
1974
Tongue
English
Weight
438 KB
Volume
7
Category
Article
ISSN
0040-5760

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The free-radical reaction of tri-n-butyl
✍ J. L. Brokenshire; K. U. Ingold πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 744 KB

## Abstract Rate constants for the tri‐__n__‐butyltin radical (**Sn Β·**) induced decomposition of a number of peroxides have been measured in benzene at 10Β°C. The values range from ∼100 __M__^βˆ’1^ sec^βˆ’1^ for di‐__t__‐butyl peroxide to 2.6 Γ— 10^7^ __M__^βˆ’1^ sec^βˆ’1^ for di‐__t__‐butyl diperoxyisophth