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Free-Radical Polymerization in Ionic Liquids: The Case for a Protected Radical

โœ Scribed by Thurecht, Kristofer J.; Gooden, Peter N.; Goel, Sarika; Tuck, Christopher; Licence, Peter; Irvine, Derek J.

Book ID
121000288
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
560 KB
Volume
41
Category
Article
ISSN
0024-9297

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## Abstract **Summary:** The controlled/living radical polymerizations of methyl acrylate in 50% v/v of an ionic liquid initiated by the alkoxyamine generated in situ from 4โ€oxoโ€2,2,6,6โ€tetramethylโ€1โ€piperidinylโ€__N__โ€oxyl (4โ€oxoโ€TEMPO) and 2,2โ€ฒโ€azoisobutyronitrile (AIBN) at 140โ€“155โ€‰ยฐC are reported