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Free-Radical Pathways in the Decomposition of Ketones over Polycrystalline TiO2: The Role of Organoperoxy Radicals

✍ Scribed by Emma Carter; Albert F. Carley; Damien M. Murphy


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
194 KB
Volume
8
Category
Article
ISSN
1439-4235

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## Abstract High‐resolution free radical polymerization kinetics was obtained using automatic continuous online monitoring of polymerization reactions (ACOMP). A sharp cross‐over from diffusion‐controlled initiation at low [monomer] to initiator decomposition control at higher [monomer] was found,