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Free Radical-initiated Reactions of Acetylene with Thiols and Carbon Monoxide

✍ Scribed by Sauer, J. C.


Book ID
126198069
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
289 KB
Volume
79
Category
Article
ISSN
0002-7863

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Rhodium-catalyzed highly selective thiof
✍ Jun-ichi Kawakami; Mitsuhiro Takeba; Ikuyo Kamiya; Noboru Sonoda; Akiya Ogawa πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 204 KB

Highly regioselective thioformylation of terminal acetylenes with thiols and carbon monoxide has been developed by the use of rhodium(I) complexes as the catalyst: formyl and thio groups are introduced into the terminal and inner positions of acetylenes, respectively. The thioformylation is performe