Free radical formation in the photooxidative alkylations of dicyanonaphthalene with alkyltriphenylborate salts

✍ Scribed by J.Y. Lan; Gary B. Schuster

• Book ID: 104226386
• Publisher: Elsevier Science
• Year: 1986
• Tongue: French
• Weight: 229 KB
• Volume: 27
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)94247-3

✦ Synopsis

One electron oxidation of alkyltriphenylborate salts leads to carbon-boron bond cleavage and the formation of free alkyl radicals. Photolysis of an Argon saturated acetonitrile solution of l,ti-dicyanonaphthalene