Free-radical copolymerizations of N-arylmaleimides. II
✍ Scribed by Patel, J. D. ;Patel, M. R.
- Book ID
- 105334715
- Publisher
- John Wiley and Sons
- Year
- 1983
- Weight
- 262 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0360-6376
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✦ Synopsis
Abstract
Free‐radical copolymerization of methyl acrylate (MA) with N‐p‐chlorophenylmaleimide (NPCMI) and N‐p‐bromophenylmaleimide (NPBMI) initiated by AIBN in cyclohexanone solution at 75°C was studied. The copolymer composition has been determined from the nitrogen content and NMR spectra of the copolymers. The reactivity ratios have been calculated by ML, FR, KT, and JJ methods. Q and e values of NPCMI and NPBMI have also been calculated by the Alfrey–Price Q‐e scheme.
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## Abstract Poly[styrene‐__co__‐(__N__‐vinylcarbazole)] copolymers with controlled molecular weights and narrow polydispersities were synthesized by nitroxide‐mediated “living” free radical copolymerization using an initiator/capping agent system consisting of benzoyl peroxide (BPO) and the stable