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Free-Radical Chemistry of Disinfection Byproducts. 3. Degradation Mechanisms of Chloronitromethane, Bromonitromethane, and Dichloronitromethane

✍ Scribed by Mincher, Bruce J.; Mezyk, Stephen P.; Cooper, William J.; Cole, S. Kirkham; Fox, Robert V.; Gardinali, Piero R.

Book ID
127007112
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
312 KB
Volume
114
Category
Article
ISSN
1089-5639

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Free-radical degradation of solid poly(m
Free-radical degradation of solid poly(methyl methacrylate) initiated by photoreduction of the chloride complexes of Fe3+. Kinetics and mechanism
✍ T.V. Pokholok; G.B. Pariysky; N.I. Zaitseva; D.Ya. Toptygin πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 619 KB

Almtract--The kinetics have been studied quantitatively and a mechanism proposed for the free-radical degradation of solid PMMA initiated by photoreduction of the chloride complexes of Fe 3+. The polymer was exposed in an inert atmosphere at 77 and 293 K to light of various spectral compositions wit