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Free Radical Bromination by the H2O2—HBr System on Water.

✍ Scribed by Ajda Podgorsek; Stojan Stavber; Marko Zupan; Jernej Iskra

Publisher
John Wiley and Sons
Year
2007
Weight
22 KB
Volume
38
Category
Article
ISSN
0931-7597

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The solvent-free side chain oxidation of
The solvent-free side chain oxidation of 4-t-butyltoluene via a photolytically assisted HBr/H2O2 system
✍ Craig W. Jones; Neil G. Carter; Steven C. Oakes; Sharon L. Wilson; Alexander Joh 📂 Article 📅 1998 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 325 KB

A process has been developed for the oxidation of 4-t-butyltoluene to 4-t-butylbenzaldehyde via an indirect route involving the formation of either 4-tbutylbenzyl bromide or 4-t-butylbenzal bromide. The organic bromides were formed using a photolytic route in the absence of solvent. The bro-HBr/H 2