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Free Enthalpy of Ternary Alloy Superlattice

✍ Scribed by Dr. F. Šrobár


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
352 KB
Volume
17
Category
Article
ISSN
0232-1300

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✦ Synopsis


Abstract

Increments due to superlattice structure are formulated for the free enthalpy and some other thermodynamic entities as functions of composition, geometry parameters and temperature. Physical contents of the general expressions, derived for simple (quasi‐regular) pseudobinary solutions, are illustrated by numerical data valid for the In~x~Ga~1–x~As/GaAs system. It is suggested that the free enthalpy of superlattice, is, at least at higher temperatures, largely dominated by the configuration entropy term. Corrections due to nonideality appear to be quite sizeable for the selected ternary alloy.


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