Free Energy Simulations of d -Xylose in Water and Methyl d -Xylopyranoside in Methanol
✍ Scribed by Höög, Christer; Widmalm, Göran
- Book ID
- 126909493
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 213 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0022-3654
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📜 SIMILAR VOLUMES
## Abstract A proposed reaction mechanism for the enzyme D‐xylose isomerase involves the ring opening of the cyclic substrate with a subsequent conformational rearrangement to an extended open‐chain form. Restrained energy minimization was used to simulate the rearrangement. In the ring‐opening ste
The strength of the intramolecular hydrogen bonds of the methyl mono-and di-0-methyl-#Lo-xylopyranosides, methyl mono-and di-O-benzyl-/3-o-xylopyranosides, benzyl di-0-benzyl-/3-o-xylopyranosides, and mono-and di-Oacetyl-J?-o-xylopyranosides was measured in terms of the frequency of the hydroxyl str