Free energy-dependence of the electronic factor in biological long-range electron transfer
β Scribed by Mikkelsen, Kurt V.; Ulstrup, Jens; Zakaraya, Merab G.
- Book ID
- 126254782
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 668 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
We analyze the conditions for the occurrence of long-range electron transfer in an isolated solvent-free supermolecule and elucidate some of the physical implications of these novel intramolecular radiationless transitions.
## Abstract Helical peptides of 8mer, 16mer, and 24mer carrying a disulfide group at the __N__βterminal and a ferrocene moiety at the __C__βterminal were synthesized, and they were selfβassembled on gold by a sulfurβgold linkage. Infrared reflectionβabsorption spectroscopy and ellipsometry confirme