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Free energies and entropies of transfer from water to methanol of cations complexed by 18-crown-6

โœ Scribed by Michael H. Abraham; How Chiong Ling


Book ID
104220363
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
208 KB
Volume
23
Category
Article
ISSN
0040-4039

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Free energies of transfer from water to
โœ B.G. Cox; P. Firman; J. Garcia-Rosas; H. Schneider ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 242 KB

A complexation scheme involving a conformational equilibrium of the ligand is proposed to explain the difference in free energies of transfer between metal complex and ligand from water to non-aqueous solvents. In a recent paper Abraham and Ling' have reported the thermodynamic parameters of transf