Free electron attachment to C60 and C70
✍ Scribed by M. Lezius; P. Scheier; T.D. Märk
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 512 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Free elecrron artachment to C, and C70 has been studied as a function of electron energy between about 0 and 14 eV. The attachment process yields copious amounts of C, and C, (with an estimated attachment cross section approaching lo-'* cm'), but neither fragment nor doubly charged anions are observed. The relative attachment cross section curves for C, and C, for energies up to 14 eV consist of broad continuum-type curves superimposed on which appear several resonance-like structures. The resonance at about zero electron energy is attributed to a nuclear-excited Feshbach resonance mechanism, whereas resonances at higher electron energies are attributed to electron-excited Feshbach resonances involving known one-electron n to rF transitions and collective excitations (plasmons) These resonances are broadened due to electron-phonon scattering, i.e. scattered electrons with non-zero energy are caged inside the fullerene. This multiple reaction sequence also accounts for the broad continuum beneath the resonance-like structures and is termed an electron/phonon-excited Feshbach resonance. The electronic structure of CG, derived from the attachment spectrum obtained, is in accordance with theoretical predictions and various electron energy loss studies.
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