Franck–Condon structure of the S0→S1 and S0→S2 transitions in norbornadiene
✍ Scribed by Zgierski, Marek Z.; Zerbetto, Francesco
- Book ID
- 125447158
- Publisher
- American Institute of Physics
- Year
- 1993
- Tongue
- English
- Weight
- 745 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.464664
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Ln the spectrum of the delayed fluorescence (DF) of pyrene, caused by triplet-triplet anndulation Tt + Tt -, Sn + SO (II = 1.2). a strong DT St -r SO and a very weak DF Sz \* SO are observed. The DF S1 -t SO IS quenched seletively by cornpounds hhe Nðylaniline or trrethylamme which do not quench
## Abstract Based on the completely optimized __S__~0~, __S__~1~, and __S__~2~ molecular geometries of azulene, the vibronic structure of the __S__~1~ ← __S__~0~ absorption as well as of the __S__~1~ → __S__~0~, __S__~2~ → __S__~1~, and __S__~2~ → __S__~0~ fluorescences is investigated theoreticall