Fragmentation Pathways of Singly- and Doubly-charged Ions in the Mass Spectra of Si-, N- and C-Substituted 1,3-Dioxa-6-aza-2-silacyclooctanes

Mass spectra of organometallic compounds

Mass spectra of organometallic compounds. 6. Energetics of fragmentations of manganese-containing ions with intact ligands in the series CH3C5H4Mn(CO)2L and CH3C5H4Mn(CO)(CS)L [L = Ph3As and Ph3Sb] [1]

✍ Avi Efraty; D. Liebman; M.H.A. Huang; C.A. Weston 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 633 KB

The mass spectra of the related series CH,C,H,-M~I(CO)~L and CH,C,H,,Mn(CO)(CS)L (L = Ph& Ph&, and Ph$b) have been examined, and the appearance potentials of all manganese-containing ions with intact ligands determined. The primary fragmentation steps in the mass spectra of these series have been as