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Fragmentation pathways of isomeric dodecenols studied by electron impact mass spectrometry

โœ Scribed by Gu Yuan; Meiyu He; Xiaoran He

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
347 KB
Volume
28
Category
Article
ISSN
1076-5174

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โœฆ Synopsis

Abstract

Electron impactโ€induced fragmentations of isomeric dodecenโ€1โ€ols were investigated using massโ€analysed ion kinetic energy (MIKE) spectrometry and highโ€resolution data. The principal fragmentation pathways of the positional isomers studied are dominated by the C๏ฃพC double bond and involve migration and radicalโ€site rearrangements along the carbon chain with the aid of consecutive rearrangements of hydrogen atoms.

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