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Fragmentation of Carbohydrate Anomeric Alkoxy Radicals: A New Synthesis of Chiral 1-Halo-1-bromo Compounds.

✍ Scribed by Concepcion C. Gonzalez; Elisa I. Leon; Concepcion Riesco-Fagundo; Ernesto Suarez

Publisher
John Wiley and Sons
Year
2003
Weight
131 KB
Volume
34
Category
Article
ISSN
0931-7597

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Fragmentation of Carbohydrate Anomeric A
Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals: New Synthesis of Chiral 1-Fluoro-1-halo-1-iodoalditols
✍ Cosme G. Francisco; Concepción C. González; Alan R. Kennedy; Nieves R. Paz; Erne 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 362 KB 👁 1 views

## Abstract A new general methodology for the synthesis of 1,1,1‐trihaloalditols by starting from 1,5‐anhydro‐2‐deoxy‐hex‐1‐enitol derivatives (glycals) is described. The halogens are introduced sequentially in each of the three different steps of the process. The fluorine is introduced in the firs