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Fragmentation of carbohydrate anomeric alkoxy radicals. A new general synthesis of cyclic ketoses

✍ Scribed by Pedro de Armas; Francisco G. Cosme; Suárez Ernesto

Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
282 KB
Volume
34
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Fragmentation of Carbohydrate Anomeric Alkoxy Radicals. A New General Method for the Synthesis of Alduronic Acid Lactones.
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Fragmentation of Carbohydrate Anomeric Alkoxy Radicals. A New General Method for the Synthesis of Alduronic Acid Lactones. -In the presence of Ph-I(O-Ac) 2 /I 2 as well as diphenylhydroxyselenium acetate/I 2 /visible light carbohydrates of type (I), (III), and (V) smoothly undergo tandem β-fragmenta