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Fragmentation of alkoxychlorocarbenes in the gas phase

✍ Scribed by Michael E Blake; Maitland Jones Jr.; Fengmei Zheng; Robert A Moss

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
70 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

In contrast to photolysis or thermal decomposition in solution, which is dominated by ionic reactions, flash vacuum pyrolysis of alkylchlorodiazirines in the gas phase generates radicals. The cyclopropylcarbinyl system is re-examined and the 1-norbornylcarbinyl system is studied for the first time.

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