Fragmentation and rearrangement of phenylcyclopropylcarbinol induced by electron impact
✍ Scribed by Keiiti Sisido; Masatosi Tanouti; Kiitirô Utimoto
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 168 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Parallel correlation between the mechanisms of mass spectral fragmentations and those of reactions in solution (1) in connection with the recent progress in the related rearrangements (2) promted us to study the mass spectral behavior of cyclopropylcarbinyl cation.
The fragmentation of cyclopropane derivatives was reported to be the cleavage of two
📜 SIMILAR VOLUMES
The fragmentation behaviour of 18 vicinally substituted aminonitropyridines was studied under electron impact conditions. The decomposition patterns were found to be strongly dependent on the position of substituents The formation of the am analogue of carbazole seems phenylamioopyridine.
The modes of fragmentation of perchlorylbenzene (C6H6C10s) and its perdeutero derivative under electron impact are reported and discussed. The occurrence of the [C,H,O]and [C,H,O]+ ions is accounted for in terms of a novel phenyl migration from chlorine to oxygen.