Fragment by fragment description of the chemical bonds in organometallic compounds
✍ Scribed by A. G. Razuvaev; G. A. Domrachev
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1986
- Tongue
- English
- Weight
- 410 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Some approaches and examples are shown to demonstrate the usefulness of inherently ‘classical’ parameters, such as bond orders and valences derivable from quantum mechanical wavefunctions, in the description and prediction of mass spectral primary fragmentation processes.
## Abstract Aspartic acid protease model peptides Z–Phe–Asp(COOH)–Thr–Gly–Ser–Ala–NHCy (1) and AdCO–Asp(COOH)–Val–Gly–NHBzl (3), and their aspartate anions (NEt~4~)[Z–Phe–Asp(COO^−^)–Thr–Gly–Ser–Ala–NHCy] (2) and (NEt~4~)[AdCO–Asp(COO^−^)–Val–Gly–NHBzl] (4), having an invariant primary sequence of