Using 25 accurately known bond-stretching force constants and bond lengths for 23 molecules, a relation of the form: F' = 37.3 r 5 35 has been obtained for carbon-nitrogen bonds. The root-mean-square deviation between the force constant values reported in the literature and those calculated from the
β¦ LIBER β¦
Fractional bonds: relations among their lengths, strengths, and stretching force constants
β Scribed by Buergi, Hans Beat; Dunitz, Jack D.
- Book ID
- 120204161
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 367 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0002-7863
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## Abstract **A reliable descriptor** of the bond strength is the stretching force constant associated with the adiabatic vibrational mode that is localized in the bond and does not couple with other vibrational modes. This is used for a comparison of Cο£ΎF^+^ and Cο£ΎO bonds (see picture).magnified im
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