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Fractal-like triplet-triplet annihilation kinetics in naphthalene-doped poly(methylmethacrylate)

✍ Scribed by E.Irene Newhouse; Raoul Kopelman


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
317 KB
Volume
143
Category
Article
ISSN
0009-2614

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✦ Synopsis


Phospha~scence decays in naphthalene-doped ~ly(methylmethac~late) are non-ex~nent~l at high dopant levels. Delayed fluorescence can be readily observed, and its long-time limiting exponential decay time is less than 112 that of the phosphorescence, suggesting an effective fractai spectral dimension of 1.0 to 1.6. Other methods of presenting the data are consistent with this observation. Evidence that these anomalous kinetics are not due merely to energetic disorder in these samples is presented.