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Fourier Transform Spectroscopy of theA2Σ+–X2ΠiTransition of AgO

✍ Scribed by L.C. O'brien; S.J. Wall; M.K. Sieber

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
108 KB
Volume
183
Category
Article
ISSN
0022-2852

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✦ Synopsis

The A 2 S / -X 2 P i near-infrared electronic transition of AgO was observed for the first time. The spectrum was recorded with the high resolution Fourier transform spectrometer associated with the McMath-Pierce Solar Telescope at Kitt Peak. The excited AgO molecules were produced in a low pressure silver hollow cathode sputter source. Constants for the A 2 S / state of 107 AgO and 109 AgO and improved X 2 P i constants for 107 AgO and 109 AgO are presented. These two states are not a unique perturber pair and they do not follow the pure precession model.

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