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Fourier Transform Spectroscopy of the O2 Herzberg Bands: II. Band Oscillator Strengths and Transition Moments

✍ Scribed by M.-F. Mérienne; A. Jenouvrier; B. Coquart; M. Carleer; S. Fally; R. Colin; A.C. Vandaele; C. Hermans


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
705 KB
Volume
202
Category
Article
ISSN
0022-2852

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Fourier Transform Spectroscopy of the O2
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Absorption spectra of molecular oxygen were measured in the laboratory under temperature and pressure conditions prevailing in the Earth's atmosphere. Spectra of pure O 2 , O 2 ϩ N 2 , and O 2 ϩ Ar were recorded in the 41 700 to 33 000 cm Ϫ1 region (240 -300 nm) at a maximal optical path difference

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The pressure shifts of the (0,0) and (1,0) bands of the b 1 S / g -X 3 S 0 g transition of oxygen (the so-called A and B bands) have been measured at room temperature in pure oxygen and in nitrogen using high-resolution Fourier transform spectroscopy. The average self-shift in the (1,0) band is 00.0