We have measured the FT spectrum of natural OCS from 4800 to 8000 cm Ϫ1 with a near Doppler resolution and a line-position accuracy between 2 and 8 ϫ 10 Ϫ4 cm Ϫ1 . For the normal isotopic species 16 O 12 C 32 S, 37 vibrational transitions have been analyzed for both frequencies and intensities. We a
Fourier Transform Spectroscopy of Carbonyl Sulfide from 3700 to 4800 cm−1and Selection of a Line-Pointing Program
✍ Scribed by S. Naı̈m; A. Fayt; H. Bredohl; J.-F. Blavier; I. Dubois
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 418 KB
- Volume
- 192
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
We have measured the Fourier transform spectrum of natural OCS from 3700 to 4800 cm-1 with a near Doppler resolution and a line-position accuracy between 4 and 8 x 10(-5) cm-1. For the normal isotopic species, 37 vibrational transitions have been analyzed for both frequencies and intensities. We also report 15 bands of OC34S, eight bands of O13CS, nine bands of OC33S, and two bands of 18OCS. Important effective Herman-Wallis terms are explained on the basis of eigenvectors. A comparison of different line-pointing programs is also presented. Copyright 1998 Academic Press.
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We have measured the FT spectrum of OCS from 1800 to \(3120 \mathrm{~cm}^{-1}\) with a resolution of \(0.007 \mathrm{~cm}^{-1}\). The spectra have been recalibrated to yield absolute uncertainties of \(3 \times 10^{-5} \mathrm{~cm}^{-1}\) throughout the whole range. For the normal isotopic species a
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