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Fourier Transform Infrared Quantitative Determination of the Total Branched Chain of Poly(Ethylene/Butyl Acrylate/Vinyl Acetate)

✍ Scribed by Lin Xianfu


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
32 KB
Volume
53
Category
Article
ISSN
0026-265X

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✦ Synopsis


An FTIR method has been developed for quantitative analysis of the total branched chain n ¯methyl of ethylene/butyl acrylate/vinyl acetate tercopolymer. In this work, mixtures of atactic polypropylene and straight-chain alkane C 27 H 56 were chosen as model compounds and the 1378 cm -1 band of the methyl side group as the key band for determination of the number of branched chains of the tercopolymer. A calibration equation correlation coefficient of 0.995 was obtained as follows:

n ¯methyl of the tercopolymer can be determined by FTIR; the results are in agreement with those determined by 1 H NMR.