High-resolution optogalvanic spectra have been observed for the first time using a Fourier transform spectrometer. Spectra from neon, argon, krypton, and xenon were observed over the range 5000 to 18000 cm-' using a modified commercial hollow cathode lamp. Signal-to-noise ratios of several hundred t
Fourier-transform hyperfine spectroscopy
โ Scribed by Th. Wacker; A. Schweiger
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 532 KB
- Volume
- 191
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A new pulsed electron nuclear double resonance technique for the measurement of hyperfine interactions is proposed. The experiment is based on burning transient holes into an inhomogeneously broadened EPR line by microwave and radio frequency pulses and detection of the hole pattern via an FID. In the spectrum obtained, each group of equivalent nuclei is represented by one peak at the hypertine frequency, independent of the nuclear spin quantum number.
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