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Fourier Transform Emission Spectroscopy of the Visible Transitions of AuCl

โœ Scribed by L.C. O'Brien; A.L. Elliott; M. Dulick

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
89 KB
Volume
194
Category
Article
ISSN
0022-2852

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โœฆ Synopsis

The visible electronic transitions of AuCl were observed at high resolution for the first time. The spectrum was recorded with the Fourier transform spectrometer associated with the McMath-Pierce solar telescope at Kitt Peak. The excited AuCl molecules were produced in a microwave discharge, with 4 Torr of helium seeded with 3% chlorine flowing over AuCl3 powder. Constants for the X1Sigma+, AOmega = 1, and BOmega = 0(+) states of Au35Cl are presented. The AOmega = 1 and the BOmega = 0(+) states may be two spin-orbit components of a 3Pi electronic state, and molecular parameters for this excited 3Pi state also are given. Copyright 1999 Academic Press.

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