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Four New Lignans with a Bicyclo[3.3.1]nonadienemethanol Skeleton from Cunninghamia lanceolata

✍ Scribed by Ching-Kuo Lee; Ming-Hsi Yeh; Tzong-Huei Lee; His-Lin Chiu; Yueh-Hsiung Kuo


Publisher
John Wiley and Sons
Year
2009
Tongue
German
Weight
175 KB
Volume
92
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Four unique bicyclo[3.3.1]nonadienemethanol lignans, designated lanceolatanins A (1), B (2), C (3), and D (4), along with one previously known compound, isolariciresinol (5), were isolated from the MeOH extracts of the heartwood of Cunninghamia lanceolata. Their structures were elucidated by application of various spectroscopic methods, including 1D‐ and 2D‐NMR techniques, to their acetylated derivatives 1a, 2a, 3a, and 4a. Their possible biosynthetic formations are also discussed.