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Four-Electrode System for Studies on Micro-ITIES Supported at the Tip of a Dual-Section Micropipette

✍ Scribed by B.Z. Yu; B. Huang; P.B. Li


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
469 KB
Volume
52
Category
Article
ISSN
0026-265X

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✦ Synopsis


Bazhang Yu, Bo Huang, and Peibiao li ({ }^{1})
Department of Chemistry, Wuhan University, Wuhan 430072, People's Republic of China Received October 21, 1993; accepted April 5, 1994

A new dual-section micropipette with a short shank and flat cross section was described and used to provide the micro-ITIES (interface between two immiscible electrolyte solutions). Four kinds of such microelectrodes have been studied by using a four-electrode microvoltammetric system with a positive feedback circuit. Experimental results for chronoamperometry, cyclic voltammetry, asymmetric sweep rate cyclic voltammetry, and stripping voltammetry have demonstrated that this system was suitable for electrochemical studies of acetylcholine chloride, vitamin (\mathrm{BI}), and tetraethylammonium tetraphenylborate transfer across a micro-ITIES, and the relevant microelectrodes could be useful in analytical determination. O 1995 Academic Press. Inc.