Four-center mechanism for olefin reactions
β Scribed by R.L. Banks; G.C. Bailey
- Book ID
- 113173790
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 244 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0021-9517
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π SIMILAR VOLUMES
## Abstract A new mechanism for gas phase ozoneβolefin reactions is proposed. The mechanism involves biradical intermediates which can react in a variety of ways. One of the possible reaction modes corresponds to the Criegie mechanism originally proposed to explain solution ozonolysis reactions and
Molecular dynamics simulations showing that high-barrier, four-center, reactions occur quite readily at elevated collision energies are presented. At such energies, the reaction is found to be super direct and the motion to, and down from, the barrier, is sudden-like. A simple kinematic model is sho