𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Four-center cyclic transition states and their associated deuterium kinetic isotope effects: hydrogenolysis of n-octyllithium

✍ Scribed by Vitale, Arturo A.; San Filippo, Joseph


Book ID
127194720
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
424 KB
Volume
104
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


The kinetics of the gas phase intramolec
✍ Kurt W. Egger πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')