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Formylation of 1,2,3,4-tetrahydro-2,4,5-trimethylpyrrolo-1-2,c]pyrimidine. Its conversions to the 7-formyl derivative with opening of the tetrahydropyremidine ring

✍ Scribed by T. N. Borisova; A. É. Aliev; E. A. Sorokina; A. A. Sinitsyna; A. V. Varlainov


Publisher
Springer US
Year
1995
Tongue
English
Weight
415 KB
Volume
31
Category
Article
ISSN
0009-3122

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The conversion of 2-formyl-3-keto-9-meth
✍ Drury Caine; John F. DeBardeleben Jr.; School of Chemistry 📂 Article 📅 1965 🏛 Elsevier Science 🌐 French ⚖ 247 KB

We have found that on irradiation in aqueous acetic acid followed by base catalyzed defomylatlon of the c-de photo-product, the 2-fonqyl dienone III is converted into the5/7-fused dienone IV in 7% overall yield. Ccmpound III was prepared from the octalone I (1) by a procedure similar to that employ