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Formation, trapping, and lifetime of the biradicals generated in the photochemistry of valeraldehyde

โœ Scribed by Encinas, M. V.; Scaiano, J. C.


Book ID
125902579
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
249 KB
Volume
100
Category
Article
ISSN
0002-7863

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Substituent and solvent effects on the l
โœ Matthew B. Zimmt; Charles Doubleday Jr.; Nicholas J. Turro ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 335 KB

Nanosecond transient absorption studies of the lifetimes (5) of several substituted 1 ,n-diphenyl-1 ,n-diyls are reported in polar and non-polar solvents. A para-bromine substituent significantly shortens r. Substitution of OH in the l-position makes the lifetime highly solvent dependent. The substi