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Formation Process of LiSn2(PO4)3, a Monoclinically Distorted NASICON-Type Structure

✍ Scribed by Martinez, Ana; Rojo, Jose M.; Iglesias, Juan E.; Sanz, Jesus; Rojas, Rosa M.


Book ID
115441284
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
644 KB
Volume
6
Category
Article
ISSN
0897-4756

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The triclinic nature of the low-temperature modification of LiSn 2 (PO 4 ) 3 , heretofore considered as monoclinic, has been proved by detailed indexing of its X-ray diffraction powder pattern. The triclinic character of most low-temperature polymorphs of NASICON-type LiMe IV 2 (PO 4 ) 3 is tentativ

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The ionic conductivity of two pellets of LiHf,(PO,), calcined at 1000 and 1100Β°C has been measured. Grain interior and grain boundary responses are distinguished in the impedance plots as well as in the real part of conductivity versus frequency plots. The activation energy associated with the motio