Formation of γ and δ lactones in irradiated beef
✍ Scribed by M. Vajdi; W. W. Nawar; C. Merritt
- Book ID
- 112823981
- Publisher
- Springer-Verlag
- Year
- 1979
- Tongue
- English
- Weight
- 161 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0003-021X
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📜 SIMILAR VOLUMES
## Abstract A one‐step transformation of __γ__‐ and __δ__‐(spiro)lactones into __γ__,__δ__‐ and __δ__,__ε__‐unsaturated aldehydes with an excess of formic acid in the vapor phase over a supported manganese catalyst is described for the first time. The scope and limitations of this new reaction are
## Abstract 1‐Trimethylsilyl‐1,3‐diyne derived trans‐bis(trimethylstannyl) enynes undergo stepwise transmetallation with methyllithium to furnish the corresponding enynyllithium reagents. The application, in various orders, of a sequence of transmetallation‐protonation‐alkylation‐hydroxyalkylation‐