Formation of β-1,4-Oligoglucosides by Certain Acetobacter Species
✍ Scribed by STEEL, ROBERT; WALKER, THOMAS K.
- Book ID
- 109593996
- Publisher
- Nature Publishing Group
- Year
- 1957
- Tongue
- English
- Weight
- 222 KB
- Volume
- 180
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/180201b0
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📜 SIMILAR VOLUMES
Sterically congested glycosides, glycosyl-13-(1--->4)-glycosides, were stereoselectively synthesized by reduction of glycosidic spiro-orthoesters with LiAIH4-AICI3. This novel transformation is especially valuable when it is applied to the preparation of mannosyl-13-(1--->4)-glycoside which must be
The 1 ,I-endoperoxide, prepared from 3-(4-methylnaphth-1 -yl)propanal by photo-oxygenation in CH2C12, gave on treatment with Ambrrlyst-15 m, 3,3,4a,pyran in 85% yield. Its structure was determined by X-ray crystal structure analysis. The 1,2,4-trioxane moiety is locked in a twist-boat conformation w