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Formation of α,β-epoxy systems from β-peroxy carbon free radicals

✍ Scribed by E.J. Corey; Greg Schmidt; Katsuichi Shimoji

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 125 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)88126-5

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✦ Synopsis

The conversion of ,6-peroxy carbon free radicals to cr,p-epoxidcs is a facile process of broad scope and may be a key step in the biosynthesis of clavulones.

In 1971 Bloodworth and Bylina reported that the reduction of the peroxy mercurial I_by sodium borohydride in aqueous tetrahydrofuran (THF) afforded in addition to the expected demercurated peroxide (2),

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