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Formation of zwitterionic ligands, ROC-(+PMe3)S2-, by nucleophilic attack of trimethylphosphine on coordinated xanthates. X-ray structure of MoO[S2C(PMe3)O-iso-Pr-S,S'](CS2CO-iso-Pr-S,S'C)

✍ Scribed by Carmona, Ernesto; Galindo, Agustin; Gutierrez-Puebla, Enrique; Monge, Angeles; Puerta, Carmen


Book ID
126844833
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
529 KB
Volume
25
Category
Article
ISSN
0020-1669

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Activation of dithioformate by iron comp
✍ Dilip V. Khasnis; Nadine Pirio; Daniel Touchard; Loïc Toupet; Pierre H. Dixneuf 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 896 KB

BH, containing iron complexes Fe(q'-HB(H),SCHSR')(CO)(PR,), (3) were prepared by reduction of Fe(q'-CS,R')(X)(CO)(PR& derivatives (2) with NaBH,. The X-ray structure of 3a (R' = R = Me) shows the cis addition of the H-and BH, fragments to the coordinated dithioformate C-S bond and that one B-H bond