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Formation of Two-dimensional Metal-water Framework Containing (H2O)20 Cluster

✍ Scribed by Ya-Guang SUN; Fu DING; Xiao-Fu GU; Wan-Zhong ZHANG; De-Zhou WEI; En-Jun GAO

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
181 KB
Volume
26
Category
Article
ISSN
0256-7660

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The PM3 quantum-mechanical method is able to model the magic water clusters (H20),, and (H20)&+. Results indicate that the H30+ ion is tightly bound within the (H20),, cluster by multiple hydrogen bonds, causing deformation to the symmetric (HzO),, pentagonal dodecahedron structure. The structures,